Catalyst behavior of plasma state in methane decomposition to hydrogen and solid carbon
Fariborz Rashidi1*, Mohammad Mahdi Moshrefi2
1Amirkabir University of Technology, Tehran, Iran
2Amirkabir University of Technology, Tehran, Iran
* Corresponding author: rashidi@aut.ac.ir
Presented at the 2nd International Symposium on Innovative Approaches in Scientific Studies (ISAS2018-Winter), Samsun, Turkey, Nov 30, 2018
SETSCI Conference Proceedings, 2018, 3, Page (s): 1142-1146
Published Date: 31 December 2018 | 1996 11
Abstract
A novel continues plasma reactor with rotating electrodes was designed and constructed to investigate methane
decomposition to hydrogen and solid carbon. This new reactor structure causes stable operation. Hydrogen is main part of
gaseous products which contain little amounts of C2 hydrocarbons while, carbon is deposited in solid phase. It was shown that
plasma has catalyst property because, it causes reaction to happen at much lower temperatures due to generation of enough
reactive species for reaction initiation and provides additional adjustable parameters toward selective production of hydrogen.
By rotation of high voltage electrode, plasma state approaches non-equilibrium state and therefore its catalytic role becomes
apparent which is beneficial in terms of energy efficiency as a major challenge facing methane decomposition. Methane
conversion and energy efficiency reached around 60% and 40% respectively.
Keywords - Methane, Decomposition, Hydrogen, Plasma
References
[1] R. Amirante, E. Cassone, E. Distaso, P. Tamburrano, Overview on recent developments in energy storage: Mechanical, electrochemical and hydrogen
technologies, Energy Conversion and Management, 132 (2017) 372-387.
[2] L. Zhou, L.R. Enakonda, M. Harb, Y. Saih, A. Aguilar-Tapia, S. OuldChikh, J.-l. Hazemann, J. Li, N. Wei, D. Gary, Fe catalysts for methane decomposition to produce hydrogen and carbon nano materials, Applied Catalysis B: Environmental, 208 (2017) 44-59.
[3] M. Pudukudy, Z. Yaakob, M.S. Takriff, Methane decomposition into COx free hydrogen and multiwalled carbon nanotubes over ceria, zirconia and lanthana supported nickel catalysts prepared via a facile solid state citrate fusion method, Energy Conversion and Management, 126 (2016) 302-315.
[4] Y. Shen, A.C. Lua, Polyol synthesis of nickel–copper based catalysts for hydrogen production by methane decomposition, International Journal of Hydrogen Energy, 40 (2015) 311-321.
[5] D.P. Serrano, J.A. Botas, P. Pizarro, I. Moreno, G. Gomez, Hydrogen production through catalytic methane decomposition promoted by pure silica materials, International Journal of Hydrogen Energy, 40 (2015) 5237-5243.
[6] A.A. Al-Hassani, H.F. Abbas, W.W. Daud, Production of CO x-free hydrogen by the thermal decomposition of methane over activated carbon: Catalyst deactivation, International Journal of Hydrogen Energy, 39 (2014) 14783-14791.
[7] V. Shapoval, E. Marotta, Investigation on Plasma‐Driven Methane Dry Reforming in a Self‐Triggered Spark Reactor, Plasma Processes and Polymers, 12 (2015) 808-816.
[8] G. Horvath, M. Zahoran, N. Mason, S. Matejcik, Methane decomposition leading to deposit formation in a DC positive CH4–N2 corona discharge, Plasma Chemistry and Plasma Processing, 31 (2011) 327-335.
[9] L.-T. Hsieh, W.-J. Lee, C.-Y. Chen, M.-B. Chang, H.-C. Chang, Converting methane by using an RF plasma reactor, Plasma chemistry and plasma processing, 18 (1998) 215-239.
[10] D.H. Lee, Y.-H. Song, K.-T. Kim, J.-O. Lee, Comparative study of methane activation process by different plasma sources, Plasma Chemistry and Plasma Processing, 33 (2013) 647-661.
[11] T. Li, C. Rehmet, Y. Cheng, Y. Jin, Y. Cheng, Experimental Comparison of Methane Pyrolysis in Thermal Plasma, Plasma Chemistry and Plasma Processing, (2017) 1-17.
[12] Z. Ghorbani, P. Parvin, A. Reyhani, S. Mortazavi, A. Moosakhani, M. Maleki, S. Kiani, Methane Decomposition Using Metal-Assisted Nanosecond Laser-Induced Plasma at Atmospheric Pressure, The Journal of Physical Chemistry C, 118 (2014) 29822-29835.
[13] M. Rahimpour, A. Jahanmiri, M.M. Shirazi, N. Hooshmand, H. Taghvaei, Combination of non-thermal plasma and heterogeneous catalysis for methane and hexadecane co-cracking: Effect of voltage and catalyst configuration, Chemical engineering journal, 219 (2013) 245-253.
[14] A. Ogata, K. Mizuno, S. Kushiyama, T. Yamamoto, Methane decomposition in a barium titanate packed-bed nonthermal plasma reactor, Plasma chemistry and plasma processing, 18 (1998) 363-373.
[15] C. Da Silva, T. Ishikawa, S. Santos, C. Alves, A. Martinelli, Production of hydrogen from methane using pulsed plasma and simultaneous storage in titanium sheet, International journal of hydrogen energy, 31 (2006) 49-54.
[16] R. Lotfalipour, A. Ghorbanzadeh, A. Mahdian, Methane conversion by repetitive nanosecond pulsed plasma, Journal of Physics D: Applied Physics, 47 (2014) 365201.
[17] R. Sanchez-Gonzalez, Y. Kim, L.A. Rosocha, S. Abbate, Methane and ethane decomposition in an atmospheric-pressure plasma jet, IEEE Transactions on Plasma Science, 35 (2007) 1669-1676.
[18] X.D. Li, H. Zhang, S.X. Yan, J.H. Yan, C.M. Du, Hydrogen production from partial oxidation of methane using an AC rotating gliding arc reactor, IEEE Transactions on Plasma Science, 41 (2013) 126-132.
[19] H. Zhang, C. Du, A. Wu, Z. Bo, J. Yan, X. Li, Rotating gliding arc assisted methane decomposition in nitrogen for hydrogen production, international journal of hydrogen energy, 39 (2014) 12620-12635.
[20] M.M. Moshrefi, F. Rashidi, Hydrogen production from methane by DC spark discharge: effect of current and voltage, Journal of Natural Gas Science and Engineering, 16 (2014) 85-89.
[21] M.M. Moshrefi, F. Rashidi, H.R. Bozorgzadeh, Use of a DC discharge in a plasma reactor with a rotating ground electrode for production of synthesis gas by partial oxidation of methane, Research on Chemical Intermediates, 41 (2015) 5941-5959.
[22] M.M. Moshrefi, F. Rashidi, H.R. Bozorgzadeh, M.E. Haghighi, Dry reforming of methane by DC spark discharge with a rotating electrode, Plasma Chemistry and Plasma Processing, 33 (2013) 453-466.
[23] M.M. Moshrefi, F. Rashidi, H.R. Bozorgzadeh, S.M. Zekordi, Methane conversion to hydrogen and carbon black by DC-spark discharge, Plasma Chemistry and Plasma Processing, 32 (2012) 1157-1168.
[24] M. Dors, H. Nowakowska, M. Jasiński, J. Mizeraczyk, Chemical kinetics of methane pyrolysis in microwave plasma at atmospheric pressure, Plasma Chemistry and Plasma Processing, 34 (2014) 313-326.
[25] J.R. Fincke, R.P. Anderson, T. Hyde, B.A. Detering, R. Wright, R.L. Bewley, D.C. Haggard, W.D. Swank, Plasma thermal conversion of methane to acetylene, Plasma Chemistry and Plasma Processing, 22 (2002) 105-136.
[26] M. Younessi-Sinaki, E.A. Matida, F. Hamdullahpur, Kinetic model of homogeneous thermal decomposition of methane and ethane, international journal of hydrogen energy, 34 (2009) 3710-3716.
[27] H.-H. Kim, Y. Teramoto, A. Ogata, H. Takagi, T. Nanba, Plasma catalysis for environmental treatment and energy applications, Plasma Chemistry and Plasma Processing, 36 (2016) 45-72.
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